Polythionic acid stress corrosion cracking pascc occurs in. Brown chemistrydepartment theamericanuniversity washington,d. The tensile stress may be residual stress resulting from heat treatment. Heat treatment method for reducing polythionic acid stress. In this chapter, the conditions for the occurrence of scc are first introduced. Stresscorrosion cracking, materials performance and. Chemical studies of polythionic acid stresscorrosion cracking. Polythionic acid stress corrosion cracking pascc is an affliction of many refineries processing sulfur containing feedstocks, and since that is the norm these days, most refiners reduce their susceptibility to pascc by selecting resistant alloys orby neutralizing exposed surfaces during shutdowns. This practice can be applied to wrought products, castings, weld metal of stainless steel or other materials that are used in environments. Polythionic stress corrosion cracking of stainless steel tube. Further progress is then a process alternating between corrosion and mechanical cracking until the material fails completely. Refer also to nace rp0170, protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during shutdown of refinery equipment. Ae monitoring from various types of stress corrosion cracking scc has been conducted for the past 15 years in our laboratory.
These characteristics are consistent with stress corrosion cracking due to polythionic acids. Precipitation reactions that occur in inconel alloy 600 were studied and correlated with corrosion behavior in nitric acid and stress corrosion cracking scc susceptibility in polythionic acid and sodium hydroxide. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. This phenomenon is usually an internal problem, occurring on the processexposed side of a piping run, vessel shell, exchanger bundle, heater tube.
Stress corrosion cracking scc can occur in a most metals and alloys due to the combined action of corrosion, tensile. The alloy is, however, susceptible to intergranular polythionic acid stress corrosion cracking. Pta scc typically does not occur during normal processing, but rather, after the equipment is shutdown and opened up for inspection i. The most common fluid that causes inter granular stress corrosion cracking igscc in petrochemical plants and refineries is polythionic acid. The item was exposed to sulfur containing natural gas in a continuous flare. Tcr engineering mumbai corrosion testing, nace, astm. Abstractlow temperature stress corrosion cracking of sensitized stainless steel, promoted by. The importance of a conjoint action of corrosion and stress as well as the nature of. Overview of polythionic acid stress corrosion cracking pascc.
Stress corrosion studies in solvent refined coal liquefaction. Further progress is then a process alternating between corrosion. Presence of cr, carbon, exposure temperatures and presence of polythionic acids play an important role in stress corrosion cracking. Polythionic acid stress corrosion cracking of type 310 stainless steel. Hydrogen induced cracking, high temperature hydrogen attack, high temperature sulfur corrosion, oxidation, flue gas corrosion, naphthenic acid corrosion, polythionic acid corrosion, caustic soda stress cracking, amines corrosion, co 2 corrosion. Figure 4 shows the results of polythionic acid stress corrosion cracking test following astm g35 on 347ap, tp321, and tp347 without stabilization. Scc is the brittle cracking of a metal due to the result of combined effects from localized corrosion and tensile stress. Presence of cr, carbon, exposure temperatures and presence of polythionic acids play. Polythionic acid is a generic term used to describe acids of the form h 2 s x o 6. Refinery environment assisted cracking flashcards quizlet. Stress corrosion cracking scc 1 is a common and dangerous form of cracking that occurs due to the combination of stress and corrosive environments. Are there any methods that can be used to give a 100% picture of the status of the pipes whilst they are mounted in the heater. Neutral chloride solutions also cause some cracking at room temperature, particularly if a thick. Ctlpolythionic stress corrosion cracking of stainless.
Alloy for resistance to polythionic acid stress corrosion cracking for. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be. Pascc stands for polythionic acid stress corrosion cracking oil refining. Polythionic acid stress corrosion cracking pascc occurs in refinery units processing sulfurous streams. Mar 23, 2010 however, polythionic acid is found to be the primary causative agent. The austenitic stainless steel tubes in these services can be susceptible to polythionic acid stress corrosion cracking. Polythionic acid may be present in petrochemical environments.
Stresscorrosion cracking of sensitized type 304 stainless. Download limit exceeded you have exceeded your daily download allowance. The cracking was found when rust stainingleaks were observed. Polythionic acid is formed in the presence of sulfur. It has been shown that, for some materials, fine pitting is needed to start the activity.
The alloys 321 and 347 are particularly useful under conditions which cause polythionic acid stress corrosion of nonstabilized austenitic stainless steel, such as alloy 304. Generally, polythionic acid stress corrosion cracking occurs in austenitic. Polythionic acid stress corrosion cracking pascc is a type of intergranular stress corrosion that affects sensitized stainless steels in refineries processing feedstocks containing sulphur. Sulfur can come from feed stock, additives or fuels. All of the cracks observed were found underneath the coke deposits. The cracks are intergranular and narrow with no significant branching.
Standard practice for evaluating stresscorrosioncracking. Cracking is due to sulfur acids forming from sulfide scale, air and moisture acting on sensitized austenitic stainless steels. A form of stress corrosion cracking normally occurring during shutdowns, startups or during operation when air and moisture are present. Presented in this report are the results of stress corrosion cracking testing per astm g36 standard practice for performing stress corrosion cracking tests in a. Stress corrosion cracking of austenitic stainless steels can occur in refinery environments where chlorides or sulfidic scales exist. What are the industrial practices being followed in. In stabilized grades of austenitic steel, titaniumniobium are added which have stronger affinity to form carbides than chromium, thus protecting corrosion resistance. Preventive measures of polythionic acid stress corrosion crackingpascc have. Iron sulfide has never been used as a medium of the test despite the fact that. Ambient temperature stresscorrosion cracking of sensitized stainless steels. It is a very severe, rapid form of intergranular scc that attacks sensitized austenitic stainless steels such a weld hazs in type 304. If the cracking has been correctly diagnosed as chloride stress corrosion cracking, and the problem is confined to small drain, flush fittings, etc. Protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during a shutdown of refinery equipment this standard practice provides mitigation methods to protect austenitic stainless steels and other austenitic alloys from pta scc that can occur during a shutdown of refinery equipment. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be vulnerable under certain conditions.
Pascc polythionic acid stress corrosion cracking oil. However, polythionic acid is found to be the primary causative agent. Tests for stress corrosion stress corrosion cracking is a timedependent process in which a metallurgically susceptible material fractures prematurely due to the synergistic interaction of a corrosive environment and sustained tensile stress at the metal surface. This paper discusses ae results of activepath dissolutiontype scc of austenitic stainless steel in chloride solution and fused salt, fluoride and polythionic acid solutions, brass. Stresses can occur for a variety of reasons, including welding, physical damage, forming, machining, grinding, heat treatment, and operating stresses. Stress corrosion cracking issues in syngas plants that may. Effects of sensitization and service fluid chemistry on polythionic. Sensitization in austenitic stainless steels causes the susceptibility of materials to intergranular corrosion igc and polythionic acid stress corrosion cracking pascc, which are wellknown phenomena in the chemical and petrochemical industries.
For practical purposes, it should be assumed that such acids can be formed by reaction of oxygen and water with oxidizable sulfur species sulfur, h2s, metal sulfides. Ambient temperature stresscorrosion cracking of sensitized. Nace sp0170 protection of austenitic stainless steels and. Pdf polythionic acid corrosion in refinery hydroprocessors. Anybody aware of any ndt method that can be used to test for the presence of polythionic acid stress corrosion cracking in heatr pipes in a fired heater. The ambient temperature tests indicated high resistance to sulfide stress corrosion cracking sscc. Nace sp0170, protection of austenitic stainless steels and other austenitic alloys from polythionic acid stress corrosion cracking during a shutdown of refinery equipment, nace international, houston, tx. Intergranular and transgranular stress corrosion cracking of the aisi 316l stainless steel at polythionic acid environment 8. Advanced search stress corrosion cracking of sensitized austenitic stainless steels in kuwait petroleum refineries.
Polythionic acid is formed in the presence of sulfur, moisture and oxygen. Tests for stresscorrosion stresscorrosion cracking is a timedependent process in which a metallurgically susceptible material fractures prematurely due to the synergistic interaction of a corrosive environment and sustained tensile stress at the metal surface. Originalityvalue the results demonstrated that scc is more severe in polythionic acid than in chloride and sour solutions. Corematerials polythionic stress corrosion cracking of. The polythionic acid sulfurous acid and hydrogen sulfide environment provides a way of evaluating the resistance of stainless steels and related alloys to intergranular stress corrosion cracking. Stress corrosion cracking of sensitized austenitic stainless. The test may not be relevant to stresscorrosion cracking in polythionic acid or caustic environments. Exposure of nonstabilized austenitic stainless steel pipe to temperatures in the sensitizing range will cause the precipitation of chromium carbides at grain boundaries. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature.
Stress corrosion cracking scc may be defined as the delayed failure of alloys by cracking when exposed to certain environments in the presence of a static tensile stress. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. C for one hour, no intergranular corrosion was observed in tp321 and tp347 welded joints. Based on this analysis the leaks were caused by cracks that initiated on the id surface. Both austenitic and straight chromium grades of stainless steels can be attacked by polythionic acid.
Stress corrosion cracking of sensitized austenitic. Pascc is defined as polythionic acid stress corrosion cracking oil refining somewhat frequently. The most damaging species identified to date are fluoride ions i and various metastable sulfur compounds. It is concluded that acidity of solutions has a relatively minor influence in promoting cracking. Polythionic acid stress corrosion cracking pascc is an affliction of many.
Once the metal is sensitized, sulfide scale on the metal can react with moisture and air, typically during shutdowns, to form polythionic acid. The mechanism of stress corrosion cracking scc involves a very complicated sequence of corrosion and fracture. Results show that alloys 304 and 304l, in the solution. Why does chloride stress corrosion cracking and pascc only. Severe stress corrosion cracking was observed in the csbp ltd, western australia 304l unlagged stainless steel absorber column of a nitric acid plant after 15 years of plant operation. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Astm a262 practice a corrosion test results will be presented for samples isothermally aged at 565 c for a duration of up to 10,000 h. Cracking of sensitized stainless steels inspectioneering. Polythionic acids form from sulfide scales exposed to oxygen and water in the stainless steel that are sensitized which can occur in most stainlesssteel tube materials after exposures to temperatures in excess of 700f to.
Astm g35 982015 standard practice for determining the. Polythionic acid stresscorrosion cracking pascc occurs in refinery units processing sulfurous streams. The temperature of the column in the region of the cracking is approximately 70c 158f. Stress corrosion cracking issues in syngas plants that may be. Abstractlow temperature stress corrosion cracking of sensitized stainless steel, promoted by aqueous. Then, the stress corrosion cracking mechanism for various materials in conditions that are susceptible is discussed in detail. This standard is directed toward preventing stress corrosion cracking scc by polythionic acids that are formed by the reaction of sulfide corrosion products with oxygen and water. How is polythionic acid stress corrosion cracking oil refining abbreviated. The most common fluid causing intergranular corrosion in hydrocarbon plants is polythionic acid. Alloy for resistance to polythionic acid stress corrosion.